《傳感材料與傳感技術(shù)叢書(shū)》中第一個(gè)影印系列MOMENTUM PRESS 的Chemical Sensors : Fundamentals of Sensing Materials & Comprehensive Sensor Technologies(6卷,影印為10冊(cè))2013年出版后,受到了專(zhuān)家學(xué)者的一致好評(píng)。為了滿(mǎn)足廣大讀者進(jìn)一步的教學(xué)和科研需要,本次影印其ChemicalSensors:Simulation and Modeling系列5卷,每卷均分為上下冊(cè))。本書(shū)是第5卷Electrochemical Sensors的上冊(cè)(第5卷1~6章內(nèi)容)。
Ghenadii Korotcenkov, received his Ph.D. in Physics and Technology of Semiconductor Materials and Devices in 1976, and his Habilitate Degree (Dr.Sci.) in Physics and Mathematics of Semiconductors and Dielectrics in 1990. For a long time he was a leader of the scientific Gas Sensor Group and manager of various national and international scientific and engineering projects carried out in the Laboratory of Micro- and Optoelectronics, Technical University of Moldova. Currently, Dr. Korotcenkov is a research professor at the Gwangju Institute of Science and Technology, Republic of Korea.
Specialists from the former Soviet Union know Dr. Korotcenkov's research results in the field of study of Schottky barriers, MOS structures, native oxides, and photoreceivers based on Group IIIH-V compounds very well. His current research interests include materials science and surface science, focused on nanostructured metal oxides and solid-state gas sensor design. Dr. Korotcenkov is the author or editor of 11 books and special issues, 11 invited review papers, 17 book chapters, and more than 190 peer-reviewed articles. He holds 18 patents, and he has presented more than 200 reports at national and international conferences.
Dr. Korotcenkov's research activities have been honored by an Award of the Supreme Council of Science and Advanced Technology of the Republic of Moldova (2004), The Prize of the Presidents of the Ukrainian, Belarus, and Moldovan Academies of Sciences (2003), Senior Research Excellence Awards from the Technical University of Moldova (2001, 2003, 2005), a fellowship from the International Research Exchange Board (1998), and the National Youth Prize of the Republic of Moldova (1980), among others.
PREFACE
ABOUT THE EDITOR
CONTRIBUTORS
PART 1: SOLID-STATE ELECTROCHEMICAL SENSORS
1 SURFACE AND INTERFACE DEFECTS IN IONIC CRYSTALS
1 Introduction
1.1 Solid Electrolytes and Electrodes for Electrochemical Sensors: A Brief Overview
1.2 Surface and Interface Properties of Ionic Solids
2 Calculation of the Surface Potential and Surface Defects Using the Stern Model
2.1 Description of the Model
2.2 Pure Crystals of the NaCl Type
2.3 Surface Potential in NaCl Crystals Containing Divalent Cations
2.4 Comparison with Experimental Data
2.5 Surface Potential and Concentration of Point Defects on Grain Boundaries of Superionic Oxide Ceramics
2.6 Surface Disorder in Terms of Energy Diagrams
2.7 Defects on Interfaces
3 Size Effects in Nanocomposite Solid Electrolytes
4 Applications in Sensors
5 Conclusions
References
2 SOLID-STATE ELECTROCHEMICAL GAS SENSORS
1 Introduction
2 Electrode Potentials
3 Types of Electrochemical Sensors
3.1 Equilibrium Potentiometric Sensors
3.2 Mixed Potentiometric Sensors
3.3 Amperometric Sensors
4 Applications
4.1 0xygen Sensors
4.2 Carbon Dioxide Sensors
4.3 NOx Sensors
4.4 SOx Sensors
4.5 Hydrogen Sensors
Acknowledgments
References
PART 2: ELECTROCHEMICAL SENSORS FOR LIQUID ENVIRONMENTS
3 MODELING AND SIMULATION OF IONIC TRANSPORT PROCESSES THROUGH IDEAL ION-EXCHANGE MEMBRANE SYSTEMS
1 Introduction
2 Theoretical Description
2.1 Ionic Transport in Ideal Ion-Exchange Membrane Systems
2.2 Electric Current Perturbations
2.3 Analytical Solutions
3 The Network Model
4 Network Simulation
4.1 Transient Response
4.2 Electrochemical Impedance
5 Conclusion
Nomenclature
4 MECHANISM OF POTENTIAL DEVELOPMENT FOR POTENTIOMETRIC SENSORS BASED ON MODELING OF INTERACTION BETWEEN ELECTROCHEMICALLY ACTIVE COMPOUNDS FROM THE MEMBRANE AND ANALYTE
5 COMPUTER MODELING OF THE POTENTIOMETRIC RESPONSE OF ION-SELECTIVE ELECTRODES WITH IONOPHORE-BASED MEMBRANES
6 MODELS OF RESPONSE IN MIXED-ION SOLUTIONS FOR ION-SENSITIVE FIELD-EFFECT TRANSISTORS
INDEX